This book constitutes the proceedings of the 25th Italian Conference on Geomatics for Green and Digital Transition, ASITA 2022, held in Genova, Italy, in June 2022. The 33 full papers included in this book were carefully reviewed and selected from 60 submissions. They were organized in topical sections as follows: Positioning, Navigation and Operational Geodesy; Data exploitation: services and tools; Geo(big)data, GeoAnalytics, AI and Decision Support; Agriculture and Forestry; Cultural Heritage and Landscape Analysis; Environmental Monitoring and Analysis; and Sustainable Development and Climate Change.